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| Zona Americana |
| Grupo 2 |
 | COLÔMBIA | 0 x 5 | BRASIL | |
| Data | Jogo | Parciais |
| 04/03 | Pablo González | 1 x 3 | Flávio Saretta | 2-6, 6-4, 4-6, 1-6 |
| 05/03 | Michael Quintero | 0 x 3 | Ricardo Mello | 3-6, 4-6, 3-6 |
| 05/03 | Quintero/González | 1 x 3 | André Sá/
Bruno Soares | 3-6, 4-6, 6-2, 1-6 |
| 06/03 | Oscar Rodríguez | 0 x 2 | André Sá | 3-6, 1-6 |
| 06/03 | Sergio Ramírez | 1 x 2 | Flávio Saretta | 6-0, 3-6, 3-6 |
| Grupo Mundial |
| Primeira rodada |
| EUA | 2 x 3 | CROÁCIA | |
| Data | Jogo | Parciais |
| 04/03 | Andre Agassi | 0 x 3 | Ivan Ljubicic | 3-6, 6-7 (0-7), 3-6 |
| 04/03 | Andy Roddick | 3 x 1 | Mario Ancic | 4-6, 6-2, 6-1, 6-4 |
| 05/03 | Bob Bryan/Mike Bryan | 1 x 3 | Mario Ancic/Ivan Ljubicic | 6-3, 6-7 (8-10), 4-6, 4-6 |
| 06/03 | Andy Roddick | 2 x 3 | Ivan Ljubicic | 6-4, 3-6, 6-7 (11-13), 7-6 (9-7), 2-6 |
| 06/03 | Bob Bryan | 2 x 1 | Roko Karanusic | 6-2, 3-6, 6-1 |
| AUSTRÁLIA | 5 x 0 | ÁUSTRIA | |
| Data | Jogo | Parciais |
| 04/03 | Lleyton Hewitt | 5 x 0 | Alexander Peya | 6-2, 6-3, 6-4 |
| 04/03 | Wayne Arthurs | 3 x 0 | Jurgen Melzer | 7-6 (7-5), 6-2, 6-4 |
| 05/03 | Wayne Arthurs/Todd Woodbridge | 3 x 2 | Knowle/Alexander Peya | 4-6, 6-3, 2-6, 6-4, 7-5 |
| 06/03 | Todd Woodbridge | 2 x 1 | Marco Mirnegg | 6-3, 4-6, 7-5 |
| 06/03 | Chris Guccione | 2 x 0 | Alexander Peya | 6-3, 6-4 |
| ROMÊNIA | 3 x 2 | BELARUS | |
| Data | Jogo | Parciais |
| 04/03 | Victor Hanescu | 1 x 3 | Max Mirnyi | 6-7 (6-8), 4-6, 6-3, 4-6 |
| 04/03 | Andrei Pavel | 3 x 0 | Vladimir Voltchkov | 6-4, 7-6 (7-2), 7-6 (7-2) |
| 05/03 | Andrei Pavel/Gabriel Trifu | 0 x 3 | Max Mirnyi/Vladimir Voltchkov | 6-7 (3-7), 3-6, 4-6 |
| 06/03 | Andrei Pavel | 3 x 1 | Max Mirnyi | 6-1, 7-6 (7-0), 4-6, 6-3 |
| 06/03 | Victor Hanescu | 3 x 0 | Vladimir Voltchkov | 7-6 (7-2), 6-4, 7-6 (8-6) |
| FRANÇA | 3 x 2 | SUÉCIA | |
| Data | Jogo | Parciais |
| 04/03 | Paul-Henri Mathieu | 3 x 0 | Max Mirnyi | 6-3, 6-4, 6-2 |
| 04/03 | Sebastien Grosjean | 0 x 3 | Thomas Johansson | 4-6, 4-6, 6-7 (1-7) |
| 05/03 | Arnaud Clement/Michael Llodra | 3 x 1 | Simon Aspelin/Jonas Bjorkman | 7-6 (7-5), 6-4, 6-7 (7-4) e 6-4 |
| 06/03 | Sebastien Grosjean | 1 x 3 | Joachim Johansson | 6-3, 1-6, 4-6, 1-6 |
| 06/03 | Paul-Henri Mathieu | 3 x 1 | Thomas Johansson | 76-1, 6-4, 6-7 (7-4), 6-4 |
| RÚSSIA | 4 x 1 | CHILE | |
| Data | Jogo | Parciais |
| 04/03 | Mikhail Youzhny | 1 x 3 | Fernando González | 6-7 (4-7), 7-5, 3-6, 6-7 (4-7) |
| 04/03 | Marat Safin | 3 x 1 | Adrian Garcia | 6-1, 3-6, 6-3, 7-6 (7-4) |
| 05/03 | Marat Safin/Mikhail Youzhny | 0 x 3 | Fernando González/Adrian Garcia | 6-3, 6-4 e 6-3 |
| 06/03 | Marat Safin | 3 x 2 | Fernando González | 7-6 (7-4), 7-6 (7-5), 1-6, 6-7 (7-3), 6-4 |
| 06/03 | Nicolay Davydenko | 2 x 0 | Paul Capdeville | 6-2, 6-1 |
| ESLOVÁQUIA | 4 x 1 | ESPANHA | |
| Data | Jogo | Parciais |
| 04/03 | Karol Beck | 3 x 0 | Feliciano López | 6-4, 7-5, 6-3 |
| 04/03 | Dominik Hrbaty | 3 x 1 | Fernando Verdasco | 6-3, 6-4, 6-7 (9-7), 6-3 |
| 05/03 | Karol Beck/Michal Mertinak | 3 x 0 | Albert Costa/Rafael Nadal | 7-6 (7-3), 6-4, 7-6 (10-8) |
| 06/03 | Michal Mertinak | 2 x 1 | Feliciano Lopez | 6-0, 6-7 (3-7), 6-4 |
| 06/03 | Kamil Capkovic | 0 x 2 | Fernando Verdasco | 2-6, 2-6 |
| HOLANDA | 3 x 2 | SUÍÇA | |
| Data | Jogo | Parciais |
| 04/03 | Sjeng Schalken | 3 x 2 | Marco Chiudinelli | 7-6 (7-4), 4-6, 6-3, 5-7, 6-2 |
| 04/03 | Peter Wessels | 3 x 1 | Stanislas Wawrinka | 7-6 (14-12), 6-7 (4-7), 7-6 (9-7), 6-4 |
| 05/03 | Dennis Van Scheppingen/Peter Wessels | 2 x 3 | Yves Allegro/Ivo Hueberger | 5-7, 4-6, 7-6 (7-5), 7-5 e 9-7 |
| 06/03 | Sjeng Schalken | 3 x 2 | Stanislav Wawrinka | 1-6, 6-2, 6-4, 2-6, 9-7 |
| 06/03 | Peter Wessels | derrota | YMarco Chiudinelli | 4-6, abandono |
| ARGENTINA | 5 x 0 | REP. TCHECA | |
| Data | Jogo | Parciais |
| 04/03 | David Nalbandián | 3 x 1 | Jiri Novak | 4-6, 6-2, 6-3, 6-4 |
| 04/03 | Guillermo Coria | 3 x 1 | Tomas Berdych | 6-3, 3-6, 6-0, 6-3 |
| 05/03 | David Nalbandian/Guillermo Cañas | 3 x 1 | Tomas Zib/Jan Hernych | 6-3, 4-6, 6-1 e 6-2 |
| 06/03 | Guillermo Coria | 2 x 0 | Jan Hernych | 6-3, 6-0 |
| 06/03 | Agustín Calleri | 2 x 0 | Tomas Zib | 6-2, 6-4 |
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