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| Zona Americana |
| Grupo 2 |
 | PERU | 1 x 2 | BRASIL | |
| Data | Jogo | Parciais |
| 10/02 | Ivan Miranda | 0 x 3 | Flávio Saretta | 2-6, 2-6, 3-6 |
| 10/02 | Luis Horna | 3 x 0 | Ricardo Mello | 6-4, 6-4, 6-4 |
| 11/02 | Horna/Miranda | 2 x 3 | Gustavo Kuerten/
André Sá | 6-4, 6-7 (6-8), 4-6, 7-5, 3-6 |
| 12/02 | Luis Horna | 3 x 1 | Flávio Saretta | 6-7 (6-8), 6-4, 6-2, 6-2 |
| 12/02 | Ivan Miranda | 1 x 3 | Ricardo Mello | 6-7 (4-7), 6-3, 4-6, 2-6 |
| Grupo Mundial |
| Primeira rodada |
| ÁUSTRIA | 2 x 3 | CROÁCIA | |
| Data | Jogo | Parciais |
| 10/02 | Jurgen Melzer | 2 x 3 | Mario Ancic | 7-6 (7-2), 7-6 (7-4), 4-6, 4-6, 3-6 |
| 10/02 | Stefan Koubek | 0 x 3 | Ivan Ljubicic | 2-6, 2-6, 4-6 |
| 11/02 | Julian Knowle/ Jurgen Melzer | 2 x 3 | Ancic/Ljubicic | 6-3, 6-3, 4-6, 4-6, 6-8 |
| 12/02 | Alexander Peya | 2 x 1 | Ivan Cerovic | 4-6, 6-2, 6-4 |
| 12/02 | Stefan Koubek | 2 x 0 | Marin Cilic | 6-1, 7-5 |
| ARGENTINA | 5 x 0 | SUÉCIA | |
| Data | Jogo | Parciais |
| 10/02 | David Nalbandian | 3 x 1 | Robin Soderling | 3-6, 6-2, 6-4, 6-1 |
| 10/02 | Jose Acasuso | 3 x 0 | Thomas Johansson | 6-1, 6-1, 6-3 |
| 11/02 | David Nalbandian/
Agustín Calleri | 3 x 1 | Jonas Bjorkman/
Simon Aspelin | 6-2, 7-6 (7-4), 2-6, 6-4 |
| 12/02 | Juan Ignacio Chela | 2 x 0 | Thomas Johansson | 6-4, 6-1 |
| 12/02 | Jose Acasuso | 2 x 0 | Jonas Bjorkman | 6-0, 6-1 |
| BELARUS | 4 x 1 | ESPANHA | |
| Data | Jogo | Parciais |
| 10/02 | Max Mirnyi | 3 x 1 | Tommy Robredo | 6-3, 6-7 (5-7), 6-3, 6-3 |
| 10/02 | Vladimir Voltchkov | 3 x 0 | David Ferrer | 6-3, 6-4, 6-3 |
| 11/02 | Mirnyi/Voltchkov | 3 x 0 | Feliciano López/ Fernando Verdasco | 7-6 (7-2), 6-4, 7-5 |
| 12/02 | Serguei Tarasevitch | 0 x 2 | David Ferrer | 1-6, 2-6 |
| 12/02 | Vladimir Voltchkov | 2 x 0 | Tommy Robredo | 7-6, (8-6), 6-3 |
| SUÍÇA | 2 x 3 | AUSTRÁLIA | |
| Data | Jogo | Parciais |
| 10/02 | Michael Lammer | 1 x 3 | Peter Luczak | 6-1, 3-6, 0-6, 3-6 |
| 10/02 | Stanislas Wawrinka | 3 x 1 | Chris Guccione | 7-5, 3-6, 6-4, 7-6 (8-6) |
| 11/02 | Yves Allegro/
George Bastl | 1 x 3 | Wayne Arthurs/
Paul Hanley | 6-7 (6-8), 4-6, 6-4, 6-7 (5-7) |
| 12/02 | Stanislas Wawrinka | 3 x 1 | Peter Luczak | 6-4, 6-2, 6-7 (7-9), 6-2 |
| 12/02 | George Bastl | 0 x 3 | Chris Guccione | 5-7, 3-6, 6-7 (7-9) |
| ALEMANHA | 2 x 3 | FRANÇA | |
| Data | Jogo | Parciais |
| 10/02 | Nicolas Kiefer | 3 x 0 | Sebastién Grosjean | 5-7, 6-7 (7-9), 0-6 |
| 10/02 | Tommy Haas | 2 x 3 | Richard Gasquet | 6-1, 4-6, 4-6, 7-6 (7-1), 3-6 |
| 11/02 | Tommy Haas/
Alexander Waske | 1 x 3 | Michael Llodra/
Arnaud Clement | 7-6 (8-6), 3-6, 4-6, 1-6 |
| 12/02 | Rainer Schuettler | 2 x 0 | Arnaud Clement | 6-4, 6-3 |
| 12/02 | Tommy Haas | 2 x 0 | Michael Llodra | 6-3, 6-3 |
| HOLANDA | 0 x 5 | RÚSSIA | |
| Data | Jogo | Parciais |
| 10/02 | Raemon Sluiter | 1 x 3 | Dmitry Tursunov | 7-6 (7-2), 4-6, 6-7 (5-7), 6-7 (5-7) |
| 10/02 | Melle van Gemerden | 0 x 3 | Nikolay Davydenko | 6-7 (6-8), 5-7, 4-6 |
| 11/02 | Raemon Sluiter/
John van Lottum | 1 x 3 | Nikolay Davydenko/
Igor Andreev | 2-6, 6-3, 4-6, 4-6 |
| 12/02 | Jesse Huta Galung | 1 x 2 | Igor Andreev | 3-6, 6-4, 6-7 (7-9) |
| 12/02 | Melle van Gemerden | 0 x 2 | Dmitry Tursunov | 6-7 (4-7), 6-7 (5-7) |
| EUA | 4 x 1 | ROMÊNIA | |
| Data | Jogo | Parciais |
| 10/02 | Andy Roddick | 1 x 3 | Andrei Pavel | 7-6 (7-2), 6-2, 6-7 (6-8), 2-6, 4-6 |
| 10/02 | James Blake | 3 x 0 | Victor Hanescu | 6-4, 7-6 (7-5), 6-2 |
| 11/02 | Bob Bryan/Mike Bryan | vence | Pavel/Hanescu | 6-2, abandono |
| 12/02 | Andy Roddick | 3 x 0 | Razvan Sabau | 6-3, 6-3, 6-2 |
| 12/02 | James Blake | 2 x 0 | Horia Tecau | 6-1, 7-5 |
| CHILE | 4 x 1 | ESLOVÁQUIA | |
| Data | Jogo | Parciais |
| 10/02 | Fernando González | 3 x 0 | Michal Mertinak | 7-6 (7-5), 7-6 (7-3), 6-3 |
| 10/02 | Nicolas Massú | 3 x 1 | Dominik Hrbaty | 6-7 (5-7), 6-3, 6-1, 7-6 (7-4) |
| 11/02 | González/Massú | 3 x 1 | Hrbaty/Mertinak | 6-2, 7-5, 3-6, 6-4 |
| 12/02 | Paul Capdeville | 2 x 0 | Victor Bruthans | 6-4, 7-5 |
| 12/02 | Adrian García | vence | Lucas Lacko | 6-4, 4-1, abandono |
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